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Beilstein J. Org. Chem. 2022, 18, 1379–1384, doi:10.3762/bjoc.18.142
Graphical Abstract
Figure 1: a) Proposed oxidative pathway for provision of GDP-ManA 5 from GDP-Man 1, C6 stereochemistry of 3 i...
Scheme 1: Syntheses of C6-modified mannose 1-phosphates 13 and 17. Conditions a) PPh3, CBr4, DCM, rt, 75%; b)...
Figure 2: Structure of 16 with ADPs rendered at the 50% probability level. Acetyl group disorder is omitted f...
Scheme 2: Evaluation of enzymatic GDP-Man synthesis using C6-modified mannose 1-phosphates 13, 17, and 18; Y+...
Figure 3: GMD function with probe 19 over 120 min (GMD (100 µg/mL), GDP sugars (50 µM), NAD+ (200 µM)). Dotte...
Beilstein J. Org. Chem. 2022, 18, 208–216, doi:10.3762/bjoc.18.24
Figure 1: Chemical structures and reported activities of viral (A), human neuraminidases (B) and Trypanosoma ...
Figure 2: Design and synthesis of potential neuraminidase and trans-sialidase inhibitors exploiting a moiety ...
Figure 3: TcTS and neuraminidase hydrolase activity (A) as well as TcTS transferase activity (B) in the prese...
Figure 4: TcTS and neuraminidase inhibition by 1,2,3-triazole-linked sialic acid derivatives 3a–h (1 mM) usin...
Figure 5: Crystal structure of TcTS (PDB code 1MS1 – coloured red) (A) and neuraminidase (PDB code 2VK6 – col...